Elnaz Milani; Fakhri Shahidi; Elham Ansarifar; Mohammad KalilianMovahed; Farideh Salehipour
Abstract
Introduction: Extruded snacks were among the most commercially successful extruded foods. Extrusion cooking is the process extensively used for the production of snacks which are mainly produced from cereal flour or starches. Extruded snacks are normally high in calories and fat with low content ...
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Introduction: Extruded snacks were among the most commercially successful extruded foods. Extrusion cooking is the process extensively used for the production of snacks which are mainly produced from cereal flour or starches. Extruded snacks are normally high in calories and fat with low content of protein, fiber, and perceived as unhealthy food to many consumers. Several attempts to improve the nutritional profile of extruded starch by using food by-products have been reported (Onwulata et al., 2001; Stojceska et al., 2008). Zizyphus jujube (Rhamnaceae) is widely distributed in Iran and the fruit of this plant has gained wide attention in native herbal medicine for the treatment of a broad range of disorders. Chemical analysis of the fruit has shown the presence of antioxidants. The high consumption of low-value meals and malnutrition among the population, especially children and adolescents, is one of the problems that exists today in society, Therefore, in this research, production of high-nutritional snack with jujube flour was studied. Materials and methods: Extrusion: In this study, a parallel twin-screw extruder (SAIXIN, model DS56, China) was applied, screw diameter of 15 mm, die diameter of 3 mm, and extrusion temperature of 180°C. Central composite statistical design was used to study the effect of feed moisture (12, 16, 18%), jujube flour addition (5, 10, 15%) and screw speed (120, 150, 180 rpm) on physicochemical properties, texture and color of expanded extrudates based on corn-wheat flour (50-50%). Bulk density was calculated using AACC (2000). The WSI of the dry solids regained through the evaporation of the supernatant obtained from the water absorption test was calculated. Textural measurement: The hardness of the extruded snacks was measured using Texture Analyzer (TAXT plus, England). The cylinder steel probe (2 mm diameter) was set to move at a speed of 1 mm/s. The samples were punctured by the probe to a distance of 8 mm. the color of samples was measured using an image processing technique (Lotfi Shirazi et al., 2020). The color parameters L* (lightness), a*(redness), b*(yellowness) values of the samples were obtained. Response surface methodology was applied for experimental data using a commercial statistical package, Design Expert (version 8.0) for the generation of response surface plot and statistical analysis of the experimental data. The second-order polynomial model was selected to predict the optimal point of the responses. Results & Discussion: Results showed that the addition of jujube flour independently increased the density 0.33, hardness 35.73 N, solubility 42% and redness (a*) 3.41, and reduced the color brightness parameter (L*) 89.1 of the samples. Similar fiber effects for pineapple pulp (Salani et al., 2014), a mixture of barley flour and grape pulp (Altan et al., 2009) and beet fiber (Lue et al., 1994) has been observed. The reduction of bulk density in samples with increasing screw speed is probably due to the starch gelatinization. When gelatinization of the starch material increased, the volume of extruded product also increased giving low density to the samples (Hagenimana et al., 2006). The WSI is a parameter which indicates the degradation of starch granules (Sharma et al., 2015). WSI decreased with increasing feed moisture and increased with increasing jujube flour or screw speed. Increase in solubility of extruded products under mild extrusion condition could result from dispersion of amylose and amylopectin molecules during gelatinization; while, the formation of low molecular weight compounds under severe conditions (low moisture and high temperature) is the main reason for an increase in flour solubility (Colonna et al., 1984). Color changing during extrusion process can provide important information regarding the degree of browning and Maillard reaction, and also pigment degradation. Increasing the feed moisture increased flour L* while it decreased the a* and ∆E of the final product. This is probably due to the decrease in mass residence time inside the extruder which causes shorter residence time necessary for non-enzymatic darkening (Lazou and Krokida, 2011). Texture is one of the most important sensory properties of extruded products in the development of snack products. Increasing the feed moisture and jujube flour increased hardness of samples. This can be explained by the effect of fiber on cell wall thickness. However, the simultaneous effect of two parameters of screw speed and jujube flour improved the properties of the snacks, by which the increase of the screw speed may cause a decrease of the starch viscosity and then lead to extrudates with reduced hardness 1.79 N. Optimum conditions for puffed snack production was found to be 13.19% feed moisture content, 6.30 % jujube flour, 122.2% screw speed.
Elham Ansarifar; Fakhri Shahidi; Mohebbat Mohebbi; Arash Koocheki; Navid Ramazanian
Abstract
Introduction: Microencapsulation has become an important technique in the food industry. One of the methods of producing microcapsules is to use layer-by-layer adsorption, in which oppositely charged polyelectrolytes are adsorbed consecutively onto a colloidal template. Creating multilayer films based ...
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Introduction: Microencapsulation has become an important technique in the food industry. One of the methods of producing microcapsules is to use layer-by-layer adsorption, in which oppositely charged polyelectrolytes are adsorbed consecutively onto a colloidal template. Creating multilayer films based on electrostatic interactions between oppositely charged components was introduced in 1991 by Decher et al. Layer-by-layer (LbL) polyelectrolyte deposition has become a popular technique for preparing polyelectrolyte capsules because of its ability to create highly tailored capsule shells through a simple, inexpensive and easily controllable adsorption process. It has been applied to produce capsules of various sizes, ranging from the nanometer to micrometer scale, with well-defined barrier properties. In this technique, assembly is driven by the electrostatic attraction of oppositely charged materials to form polyelectrolyte shells. The structure of the polyion layered capsule shell is determined mainly by the electrostatic interactions between the polyions used. The mechanical strength and permeability of the capsules can be controlled by varying the number of layers or by changing the characteristics of the encapsulating materials. The purpose of this study was to produce microcapsules using supramolecular assemblies consisting of common food ingredients such as soy protein isolate (SPI) and high methoxyl (HM) pectin. Moreover, some features of the developed microcapsulation were studied.
Materials and methods: SPI fibrils were prepared based on the method developed by Akkermans et al., (2008) and its morphology was studied using transmission electron microscopy (TEM) and atomic force microscopy (AFM). 0.5% (w/w) SPI fibril and pectin solutions were prepared by mixing at pH 3.5 were left stirring overnight. The LbL process for the production of microcapsules with protein fibril-reinforced nanocomposite shells has been described in Humblet-Hua et al., 2012. It starts with the production of A 2% w/w emulsion of (0.05 gr diacetyl in 1.95gr sun flower oil) in fibril SPI solution is produced using a homogenizer with a rotor-stator dispersion tool using a setting of 13500 rpm for 90 S. Because the proteins are below their isoelectic point, the emulsion droplets have a positive charge. To avoid interactions between the nonadsorbed SPI and the biopolymer of the next layer, the droplets are separated from the serum by means of centrifugation. After the isolation, the droplets are dispersed into a solution of HMP. The HMP is negatively charged at the chosen pH of 3.5. The bilayered droplets can be isolated again and dispersed in a fibril solution to deposit a third layer of a positively charged mixture of SPI fibrils. Subsequently, additional layers of HMP and SPI fibrils can be deposited by repeating the same procedures. Some features of the microcapsulation, including size, zeta potential, and morphology and release kinetics were studied.
Results & discussion: TEM and AFM micrographs showed that SPI fibrils obtained had a contour length of a few hundred nanometers, thickness of between 1 and 10 nm and its structure is highly branched. One of the most common problems reported in previous studies using the LbL technique to produce multilayer particles, is the tendency for flocculation. In the present system, this problem was not observed. The size distribution of isolated emulsion droplets (templates) did not change significantly from 1-layer droplets to 5-layer droplets. In other words, the emulsion droplets were stable against flocculation after applying more layers of polyelectrolytes. The Sauter mean diameters D (3, 2) of these droplets fluctuated between 5 and 7 µm and slightly increased as the number of layers increased; noting that the emulsion droplets were poly-dispersed. Another possible problem that may occur using the LbL technique is the complex formation between non-adsorbed protein and the pectin molecules. These complexes with a typical diameter smaller than 1 mm were not detected here. Result showed that the zeta potential distribution of emulsion droplets reverses from about plus (+) 30 mV (odd number of layers with SPI fibrils as outer layers) to about negative (-) 20 mV (even number of layers with HMP as outer layers) confirming the layer-by-layer adsorption based on electrostatic attraction. Comparing SEM of microcapsules with various numbers of layers, an improvement in shell strength can be seen. Indentation is observed on 1-layer microcapsules showing that there are defects on the shell. They could be formed during the drying process or they are shell defects due to incomplete coverage of materials, meaning more layers are needed to fully cover the microcapsule shell. These defects are seen less on 5-layer microcapsules. These observations indicate that the more layers the more consistent the shells and the more resistant. It is against the physical drying process. Results showed that the time of the maximum in release shifts to higher values as the number of layers of the capsules increased. We clearly see that increasing the number of layers in the shell of the capsules leads to a delay of the release of diacetyl and maximum release time as a function of the number of layers is increasing steadily which show the release can be delayed even more by adding additional layers. These results prove that the release properties of the multilayer capsules can be tuned by controlling the number of layers in the shell of the capsules. The modeling results of four different kinetic models are indicated that the Rigter–Peppas was an appropriate model for diacetyl release prediction from multilayer microcapsulation. It could be attributed that the release mechanism is mostly governed by the Swelling–Fickian mechanism.
Conclusion: In this study, the microcapsules were produced using the LbL technique and food-grade SPI fibrils and HMP. The microcapsules had a poly-disperse size distribution. No flocculation of microcapsules during applying of additional layers was observed. It was found that increasing the number of layers, decreases the release rate of diacetyl. The diacetyl release data were kinetically evaluated by zero-order, first-order, Higuchi, and Rigter–Peppas models and the results showed that the release phenomena is mostly governed by the Fickian mechanism. Since the materials are food-grade, the applications of these microcapsules can include food products or pharmaceutical purposes.
Behdad Shokrollahi Yanchedhmeh; Mohebbat Mohebbi; Mehdi Varidi; Elham Ansarifar
Abstract
In recent decades, as the result of industrial life, consuming fried and fast foods have increased significantly. Excessive use of fat, especially saturated fats and trans fatty acids is one of the important factors that increases heart diseases, weight gain, and cancers. Therefore, using effective methods ...
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In recent decades, as the result of industrial life, consuming fried and fast foods have increased significantly. Excessive use of fat, especially saturated fats and trans fatty acids is one of the important factors that increases heart diseases, weight gain, and cancers. Therefore, using effective methods for decreasing fat absorption not only retains desirable features but also seems essential. In this study, the effect of subtituting wheat flour with lentil flour on the batter formulation (in different level of 10, 25 and 50 percent) on the rheological properties of batter, amount of moisture and oil content, and color of fried crusts investigateded by using a deep-fried crust model at three temperature (140, 160 and 180oc) and for 90, 180, 270 and 360 s frying times. Consistency index showed a significant increase by increasing subtitution of lentil flour in batter formulation. Moreover, all the batters showed shear-thinning behaviour. The findings indicated that Batter formulations, temperature and frying time significantly (p < 0.05) affected moisture content, oil content and color of fried Crusts. Results of the study indicated that as frying time increased, the amount of moisture content reduced and increased the oil content of the final product. Also, with increasing substitution of lentil flour, moisture removal decreased and therefore, oil uptake decreased. 50% lentil flour substituted samples was found to be an effective formulation in decreasing oil content of fried crusts at all the times . Conrol sampel showed the lowest moisture content and highest oil content among all the formulations. 50% lentil flour substituted samples was found to be an effective formulation in decreasing oil content of fried crusts at all the times . Conrol sampel showed the lowest moisture content and highest oil content among all the formulations. Temperature leaded to an increase in moisture removal and an increase in oil content. By increasing frying time, temperature and subtitution of lentil flour in battre formulation, L*parameter decreased and a* and b* increased.
Elham Ansarifar; Mohebbat Mohebbi; Fakhri Shahidi; Mehdi Varidi
Abstract
The objective of this study was to evaluate the effect of frying temperature, time and different batter formulations on the rheological properties and mass transfer during deep fat frying of Kurdish cheese nuggets. The effects of white egg (0, 5, 10%) addition to the batter formulation of cheese nuggets ...
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The objective of this study was to evaluate the effect of frying temperature, time and different batter formulations on the rheological properties and mass transfer during deep fat frying of Kurdish cheese nuggets. The effects of white egg (0, 5, 10%) addition to the batter formulation of cheese nuggets and frying at 150, 170 and 190◦C for 0, 1, 2, 3 and 4 min have been investigated. The results showed an interaction effect of these processing conditions on mass transfer. The most reduction in fat absorption was observed when samples were coated with batter containing 10% white egg and fried at 150 ◦C. The kinetic model based on the Fick’s law was used to describe moisture transfer data. The effective moisture diffusivity of batter without white egg was within the range of 3.97×10−8 and 7.51×10−8m2/s with R2 between 0.91 and 0.86 .In the samples coated with the batter including white egg, the effective diffusivity ranged between 2.26×10−8 and 5.96×10−8m2/s with R2 between 0.98 and 0.87, and fat transfer rate constant was between 1.1×10−3 and 8.9×10−3 s−1 with R2 from 0.82 to 0.99. Activation energy obtained from the Arrhenius plot for the effective moisture diffusivity of batter with and without white egg was 30.01 kJ/mol and ranged from 38.42 to 36.52 kJ/mol, respectively
